This was also shot around 1pm -2pm.
you can see the harsh shadows being pushed forward from behind the subject. An assistant held a 42inch Octabox with single speed light 45 degrees above him. About a foot or 2 away from his face (very close). The light and assistant were Photoshopped out of the image. Also the details in the sky were brought back in post. The settings were approximately 1/200, f5.6-f7 and ISO 100.
Good job! Love the exposure here