This was shot with natural light. The photo was taken from outside the window with the bride standing inside and the groom standing outside behind camera right. His reflection was used to give a "double exposure" look to the image. No photoshop. Just Lightroom color grading and DB used to make his reflection pop.
Nikon Z8
z 85mm f1.2
Shot at f4.5, ISO 500, 1/80
Oh, very nicely done indeed. Bet the couple LOVE this.
I almost feel like she is trying to forget about him. As if he was an ex, or wishing that he would be. The emotions are too sad for me... almost like a still from a 'Lifetime for Woman' original movie.