Sunset is distinct from twilight, which is divided into three stages. The first one is civil twilight, which begins once the Sun has disappeared below the horizon, and continues until it descends to 6 degrees below the horizon. The early to intermediate stages of twilight coincide with predusk. The second phase is nautical twilight, between 6 and 12 degrees below the horizon. The third phase is astronomical twilight, which is the period when the Sun is between 12 and 18 degrees below the horizon. Dusk is at the very end of astronomical twilight, and is the darkest moment of twilight just before night. Finally, night occurs when the Sun reaches 18 degrees below the horizon and no longer illuminates the sky.
Basic editing of light, shadows a minor color correction. Sony a200, kit lens.